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Water vapor is, aside from carbon dioxide, the major fossil fuel combustion by-product. Depending on its concentration in the exhaust gas mixture as well as on the exhaust gas pressure, its condensation temperature can be derived. For typical gasoline engine stoichiometric operating conditions, the water vapor dew point lies at about 53 °C. The exhaust gas mixture does however contain some pollutants coming from the fuel, engine oil, and charge air, which can react with the water vapor and affect the condensation process. For instance, sulfur trioxide present in the exhaust, reacts with water vapor forming sulfuric acid. This acid builds a binary system with water vapor, which presents a dew point often above 100 °C. Exhaust composition after leaving the combustion chamber strongly depends on fuel type, engine concept and operation point. Furthermore, the exhaust undergoes several chemical after treatments.

The formation of soot during the first phase and the oxidation of soot during the later phase of the combustion in a direct-injection diesel engine have been investigated in detail by an extinction method. The experiments were performed in a 1.9 l near-production high-speed four-cylinder in-line direct-injection diesel engine for passenger cars for different rates of exhaust gas recirculation (EGR) and for different fuels. The measurements result in crank angle resolved and cycle-averaged soot mass concentrations in the piston bowl and the combustion chamber. The results show that with increasing EGR-rates the amount of soot formed is increased only slightly but the amount of soot oxidized during combustion decreases significantly. This is assumed to be the main reason for the increase of soot in the exhaust gas with increasing EGR-rates.

In this paper the emissions of regulated and unregulated exhaust gas components of a fleet of diesel passenger cars measured at Volkswagen in the eighties are compared with the results of a new investigation on modern direct-injection diesel vehicles. The potential of improved diesel fuels to reduce emissions is also examined. The emissions of regulated exhaust gas components as well as fuel consumption have been reduced significantly in the last years as a result of the systematic further development of conventional swirl chamber engines and exhaust gas after-treatment as well as the introduction of SDI/TDI engines. As was to be expected, this has also had a positive effect on the emissions of unregulated exhaust gas components. It has been possible, for example, to reduce the polycyclic aromatic hydrocarbons adsorbed on diesel particulates by more than 95%.

Laser-induced exciplex fluorescence has been applied to the mixture formation process in the combustion chamber of an optically-accessible four-cylinder in-line spark-ignition engine in order to distinguish between liquid and vapor fuel distribution during the intake and compression stroke for different injection timings. The naphthalene/N,N,N′N′-tetramethyl p-phenylene diamine (TMPD) exciplex system excited at 308nm with a broadband XeCl excimer laser is used to obtain spectrally-separated, single-shot fluorescence images of the liquid or vapor phase of the fuel. For different timings of the fuel injector this technique is applied to obtain crank-angle-resolved images of the resulting mixture in the combustion chamber. The fluorescence light is detected with an intensified slow-scan CCD-camera equipped with appropriate filters.

The reduction of both harmful emissions (CO, HC, NOx, etc.) and gases responsible for greenhouse effects (especially CO2) are mandatory aspects to be considered in the development process of any kind of propulsion concept. Focusing on ICEs, the main development topics are today not only the reduction of harmful emissions, increase of thermodynamic efficiency, etc. but also the decarbonization of fuels which offers the highest potential for the reduction of CO2 emissions. Accordingly, the development of future ICEs will be closely linked to the development of CO2 neutral fuels (e.g. biofuels and e-fuels) as they will be part of a common development process. This implies an increase in development complexity, which needs the support of engine simulations. In this work, the virtual modeling of real fuel behavior is addressed to improve current simulation capabilities in studying how a specific composition can affect the engine performance.

After the success of the 4-cylinder 1.9-liter TDI and SDI direct-injection diesel engines in the Passat, Jetta and Polo classes, a new 3-cylinder TDI has been developed for use in the "Lupo 3L,' a compact car with a fuel consumption of 3 liters per 100 km. A new injection system with unit injectors, together with a fully electronically controlled engine management system featuring drive-by-wire- technology, a turbocharger with variable turbine geometry and a fully automated mechanical gearbox and clutch, for the first time ensures the potential to meet the stringent D4 exhaust emissions level and to achieve excellent fuel economy. The wheel-torque based engine and gearbox management systems optimize engine operation in terms of efficiency and emissions.